Unless the CALL is the only thing in the query, you need to explicitly YIELD variables from the call (using call apoc.help('create.rel') shows us this procedure yields a
rel` variable), and as in the message you can't end the query with a CALL, it needs to be a writing clause or a return. If you need the equivalent of a no-op then you can remove a non-existent property from a node or relationship:
LOAD CSV WITH HEADERS FROM "file:///relations.csv" AS row
MATCH (f:Node), (s:Node)
WHERE f.Name = row.FromNode
AND s.Name = row.ToNode
CALL apoc.create.relationship(f, row.RelationType,{}, s) YIELD rel
REMOVE rel.noOp